You could use a DataView on the Web app
Dim dv As DataView = New DataView(YourDataTableHere)
By using the dataView you have far greater control over the two applications, they are essentially working in tandem, but the data remains separate until you confirm all changes made to the DataView. I would suggest you read MSDN documentation just to make sure it is suitable for your scenario.
The best point about DataViews is that you have great control over the types of modifications made; such as added, modified or deleted.
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